It seems you've got a case where a DB got encrypted by the SQL server automatically, such as in case of tempdb, once Transparent Data Encryption (TDE) was enabled. I am seeing exactly same case in my test instance of SQL Server 2012 with tempdb.
MSDN: The tempdb system database will be encrypted if any other database on the instance of SQL Server is encrypted by using TDE.
is_encrypted = 0 I believe reflects the fact that DB was encrypted automatically, not by issuing ALTER command.
Here is what MSDN says about this parameter: Indicates whether the database is encrypted (reflects the state last set by using the ALTER DATABASE SET ENCRYPTION clause).
percent_complete = 0 is expected when there is no ongoing encryption. From MSDN: Percent complete of the database encryption state change. This will be 0 if there is no state change.
encryption_state = 3 looks to be the ultimate hint in answering the question. MSDN: Indicates whether the database is encrypted or not encrypted, 3 = Encrypted.
MSDN TDE page itself suggests to use sys.dm_database_encryption_keys to verify if DB is encrypted or not.
And finally, here is a really handy script from John Magnabosco's post showing which DBs are encrypted with TDE and which are not (encryption_state = 3 is the teller):
SELECT
db.name,
db.is_encrypted,
dm.encryption_state,
dm.percent_complete,
dm.key_algorithm,
dm.key_length
FROM
sys.databases db
LEFT OUTER JOIN sys.dm_database_encryption_keys dm
ON db.database_id = dm.database_id;
GO
Hopefully this makes it less confusing now.