Autofit does not work on cells with strings.
Try to replace the Column-line in your example by the following code:
<xsl:for-each select="/*/*[1]/*">
<Column>
<xsl:variable name="columnNum" select="position()"/>
<xsl:for-each select="/*/*/*[position()=$columnNum]">
<xsl:sort select="concat(string-length(string-length(.)),string-length(.))" order="descending"/>
<xsl:if test="position()=1">
<xsl:if test="string-length(.) < 201">
<xsl:attribute name="ss:Width">
<xsl:value-of select="5.25 * (string-length(.)+2)"/>
</xsl:attribute>
</xsl:if>
<xsl:if test="string-length(.) > 200">
<xsl:attribute name="ss:Width">
<xsl:value-of select="1000"/>
</xsl:attribute>
</xsl:if>
</xsl:if>
<xsl:if test = "local-name() = 'Sorteer'">
<xsl:attribute name="ss:Width">
<xsl:value-of select="0"/>
</xsl:attribute>
</xsl:if>
</xsl:for-each>
</Column>
</xsl:for-each>
Explanation: It sorts on string-length (longest string first), take first line of sorted strings, take length of that string * 5.25 and you will have a reasonable autofit.
Sorting line:
<xsl:sort select="concat(string-length(string-length(.)),string-length(.))" order="descending"/>
explanation: if you just sort on length, like
<xsl:sort select="string-length(.)" order="descending"/>
because the lengths are handled as strings, 2 comes after 10, which you don't want. So you should left-pad the lengths in order to get it sorted right (because 002 comes before 010). However, as I couldn't find that padding function, I solved it by concattenating the length of the length with the length. A string with length of 100 will be translated to 3100 (first digit is length of length), you will see that the solution will always get string-sorted right. for example: 2 will be "12" and 10 will be "210", so this wil be string-sorted correctly. Only when the length of the length > 9 will cause problems, but strings of length 100000000 cannot be handled by Excel.
Explantion of
<xsl:if test="string-length(.) < 201">
<xsl:attribute name="ss:Width">
<xsl:value-of select="5.25 * (string-length(.)+2)"/>
</xsl:attribute>
</xsl:if>
<xsl:if test="string-length(.) > 200">
<xsl:attribute name="ss:Width">
<xsl:value-of select="1000"/>
</xsl:attribute>
</xsl:if>
I wanted to maximize length of string to about 200, but I could not get the Min function to work, like
<xsl:value-of select="5.25 * Min((string-length(.)+2),200)"/>
So I had to do it the dirty way.
I hope you can autofit now!