Add two empty label controls into your Repeaters ItemTemplate where you'd want your div tags to be.
Then add an ItemDataBound event to the Repeater.
Then add this code into the ItemDataBound event:
Protected Sub Repeater1_ItemDataBound(ByVal sender As Object, ByVal e As System.Web.UI.WebControls.RepeaterItemEventArgs)
If (e.Item.ItemType = ListItemType.Item) Or (e.Item.ItemType = ListItemType.AlternatingItem) Then
If e.Item.ItemIndex Mod 5 = 0 Then
Dim lblDivStart As Label = CType(e.Item.FindControl("lblDivStart"), Label)
Dim lblDivEnd As Label = CType(e.Item.FindControl("lblDivEnd"), Label)
lblDivStart.text = "<div>"
lblDivEnd.text = "</div>"
End If
End If
End Sub
Note - This will need some tweaking to handle the first div and you may need to do something like If (e.Item.ItemIndex + 1) Mod 5 = 0 to get the divs to show up exactly where you want them.
For more info:
DataListItem.ItemIndex Property
DataList.ItemDataBound Event