You shouldn't check for an exact version number. This will change in the future (as was the case for 4.0 > 4.5). Instead use the codes from the deployment guide.
In addition to that you should try to handle the reboot from .Net 4.5.
Function CheckAndInstallDotNet
; Magic numbers from http://msdn.microsoft.com/en-us/library/ee942965.aspx
ClearErrors
ReadRegDWORD $0 HKLM "SOFTWARE\Microsoft\NET Framework Setup\NDP\v4\Full" "Release"
IfErrors NotDetected
${If} $0 >= 378389
DetailPrint "Microsoft .NET Framework 4.5 is installed ($0)"
${Else}
NotDetected:
DetailPrint "Installing Microsoft .NET Framework 4.5"
SetDetailsPrint listonly
ExecWait '"$INSTDIR\Tools\dotNetFx45_Full_setup.exe" /passive /norestart' $0
${If} $0 == 3010
${OrIf} $0 == 1641
DetailPrint "Microsoft .NET Framework 4.5 installer requested reboot"
SetRebootFlag true
${EndIf}
SetDetailsPrint lastused
DetailPrint "Microsoft .NET Framework 4.5 installer returned $0"
${EndIf}
FunctionEnd