go to http://www.gadm.org/download, download the adm0 file for the Netherlands
Combine that polygon (as the inner ring(s)) with a polygon that covers the whole earth
use the winding reversal tool to reverse any inner polygons that don't wind opposite the outer ring.
zip up the resulting kml, rename to kmz. Display on the map using geoxml3
Code:
function initialize() {
var map = new google.maps.Map(
document.getElementById("map_canvas"), {
center: new google.maps.LatLng(85.4419, -122.1419),
zoom: 13,
mapTypeId: google.maps.MapTypeId.ROADMAP
});
var geocoder = new google.maps.Geocoder();
var geoXml = new geoXML3.parser({
map: map,
zoom: false,
});
geoXml.parse("http://www.geocodezip.com/geoxml3_test/kmz/nld_adm0_inverted.kmz");
google.maps.event.addListener(geoXml,'parsed', function() {
geocoder.geocode( { 'address': "Netherlands"}, function(results, status) {
if (status == google.maps.GeocoderStatus.OK) {
map.fitBounds(results[0].geometry.viewport);
} else {
alert("Geocode was not successful for the following reason: " + status);
}
});
})
}
google.maps.event.addDomListener(window, "load", initialize);
Working example
To restrict it to be always displayed on the map see this page from Mike Williams' v2 tutorial
working example