The Adler-32 algorithm is to compute
A = 1 + b1 + b2 + b3 + ...
and
B = (1 + b1) + (1 + b1 + b2) + (1 + b1 + b2 + b3) + ... = 1 + b1 + 2 * b2 + 3 * b3 + ...
and report them modulo m. When m is prime, the numbers modulo m form what mathematicians call a field. Fields have the handy property that for any nonzero c, we have a = b if and only if c * a = c * b. Compare the times table modulo 6, which is not a prime, with the times table modulo 5, which is:
* 0 1 2 3 4 5
0 0 0 0 0 0 0
1 0 1 2 3 4 5
2 0 2 4 0 2 4
3 0 3 0 3 0 3
4 0 4 2 0 4 2
5 0 5 4 3 2 1
* 0 1 2 3 4
0 0 0 0 0 0
1 0 1 2 3 4
2 0 2 4 1 3
3 0 3 1 4 2
4 0 4 3 2 1
Now, the A part gets fooled whenever we interchange two bytes -- addition is commutative after all. The B part is supposed to detect this kind of error, but when m is not a prime, more locations are vulnerable. Consider an Adler checksum mod 6 of
1 3 2 0 0 4
We have A = 4 and B = 1. Now consider swapping b2 and b4:
1 0 2 3 0 4
A and B are unchanged because 2 * 3 = 4 * 0 = 2 * 0 = 4 * 3 (modulo 6). One can also swap 2 and 5 to the same effect. This is more likely when the times table is unbalanced -- modulo 5, these changes are detected. In fact, the only time a prime modulus fails to detect a single swap is when two equal indexes mod m are swapped (and if m is big, they must be far apart!).^ This logic can also be applied to interchanged substrings.
The disadvantage in using a smaller modulus is that it will fail slightly more often on random data; in the real world, however, corruption is rarely random.
^ Proof: suppose that we swap indexes i and j with values a and b. Then ai + bj = aj + bi, so ai - aj + bj - bi = 0 and (a - b)*(i - j) = 0. Since a field is an integral domain, it follows that a = b (values are congruent) or i = j (indexes are congruent).
EDIT: the website that Unknown linked to (http://www.zlib.net/zlib_tech.html) makes it clear that the design of Adler-32 was not at all principled. Because of the Huffman code in a DEFLATE stream, even small errors are likely to change the framing (because it's data-dependent) and cause large errors in the output. Consider this answer a slightly contrived example for why people ascribe certain properties to primes.