Day is the day of the month.
Weekday is the day of the week (0 and 7 == Sunday).
For you, you need:
<key>StartCalendarInterval</key>
<array>
<dict>
<key>Weekday</key>
<integer>1</integer>
<key>Hour</key>
<integer>8</integer>
<key>Minute</key>
<integer>0</integer>
</dict>
<dict>
<key>Weekday</key>
<integer>2</integer>
<key>Hour</key>
<integer>8</integer>
<key>Minute</key>
<integer>0</integer>
</dict>
<dict>
<key>Weekday</key>
<integer>3</integer>
<key>Hour</key>
<integer>8</integer>
<key>Minute</key>
<integer>0</integer>
</dict>
<dict>
<key>Weekday</key>
<integer>4</integer>
<key>Hour</key>
<integer>8</integer>
<key>Minute</key>
<integer>0</integer>
</dict>
<dict>
<key>Weekday</key>
<integer>5</integer>
<key>Hour</key>
<integer>8</integer>
<key>Minute</key>
<integer>0</integer>
</dict>
</array>
Not quite as elegant as cron...