Once logged in to your paid seller account... in the upper right corner of the screen, Settings > User Permissions, then under the text "Amazon MWS Developer Access Keys" press the button "Visit Developer Credentials".
If you already have a Developer ID but it is no longer working, you have to apply again here: https://sellercentral.amazon.com/mws/register/warning
Before applying, I suggest you study hard the information in these links. I think if you answer even one of the questions wrong while applying for the developer ID, you will be denied. Also, if you get denied, they don't tell you the reason
http://docs.developer.amazonservices.com/en_US/dev_guide/DG_DataProtectionPolicy.html
http://docs.developer.amazonservices.com/en_US/dev_guide/DG_AcceptableUsePolicy.html
In addition, FYI:
It used to be that anyone with a paid seller account could get developer credentials just by clicking some buttons. However, Amazon is now vetting developers with a more through process which could take up to 30 days.
merchant ID, Marketplace ID, AWS Access Key ID, Secret Key
But no developer account number. Any ideas? – Haynie