There are a couple of ways you could do this.
Absolute Positioning
Like others have suggested, if you give the element that you want to stretch across the page CSS properties of 100% width and absolute position, it will span the entire width of the page.
However, it will also be situated at the top of the page, probably obscuring your other content, which won't make room for your now 100% content. Absolute positioning removes the element from the document flow, so it will act as though your newly positioned content doesn't exist. Unless you're prepared to calculate exactly where your new element should be and make room for it, this is probably not the best way.
Images: you can also use a collection of images to get at what you want, but good luck updating it or making changes to the height of any part of your page, etc. Again, not great for maintainability.
Nested DIVs
This is how I would suggest you do it. Before we worry about any of the 100% width stuff, I'll first show you how to set up the 70% centered look.
<div class="header">
<div class="center">
// Header content
</div>
</div>
<div class="mainContent">
<div class="center">
// Main content
</div>
</div>
<div class="footer">
<div class="center">
// Footer content
</div>
</div>
With CSS like this:
.center {
width: 70%;
margin: 0 auto;
}
Now you have what appears to be a container around your centered content, when in reality each row of content moving down the page is made up of a containing div, with a semantic and descriptive class (like header, mainContent, etc.), with a "center" class inside of it.
With that set up, making the header appear to "break out of the container div" is as easy as:
.header {
background-color: navy;
}
And the color reaches to the edges of the page. If for some reason you want the content itself to stretch across the page, you could do:
.header .center {
width: auto;
}
And that style would override the .center style, and make the header's content extend to the edges of the page.
Good luck!