This answers your actual question, but not your intent.
You asked about replacing the nth occurrence of a word (but seemed to mean "within a line"). Here's an answer for the question as asked, in case someone finds it like I did =)
For weird tasks (like needing to replace every 12th occurrence of "dog" with "parrot"), I like to use recursive recordings.
First blank the recording in @q
qqq
Now start a new recording in q
qq
Next, manually do the thing you want to do (using the example above, replace the 12th occurrence of "dog" with "parrot"):
/dog
nnnnnnnnnnn
delete "dog" and get into insert
diwi
type parrot
parrot
Now play your currently empty "@q" recording
@q
which does nothing.
Finally, stop recording:
q
Now your recording in @q calls itself at the end. But because it calls the recording by name, it won't be empty anymore. So, call the recording:
@q
It will replay the recording, then at the end, as the last step, replay itself again. It will repeat this until the end of the file.
TLDR;
qq
q
/dog
nnnnnnnnnnndiwiparrot<esc>
@q
q
@q
s///
: vim.1045645.n5.nabble.com/… – Aric