Well, the code won't compile, but I'll just ignore that...
If I'll just look at the line:
throw new Exception(InvalidoperationException);
1st of all, according to MSDN there is no such constructor. So I will assume you meant the constructor: Exception(String msg, Exception innerException). Meaning:
throw new Exception("blabla", InvalidoperationException);
The exception that is being thrown is of type Exception and not InvalidOperationException. So ONLY catch(Exception x) can catch it.
If you would've thrown InvalidoperationException than the way you wrote the order of the catches, the Exception class would get caught first.
The order of the catches does matter.
The best advice I can give you is simply try it yourself and see what happens.