The built in version of as is outdated. (In OS X 10.8.3)
/usr/libexec/as/x86_64/as -v
Apple Inc version cctools-839, GNU assembler version 1.38
There does not seem to exist a version of gas for OS X. (See:
Installing GNU Assembler in OSX)
Using the clang assembler via a script hack (as pointed out by Conrado PLG) is one workaround. However, it does require administrator privileges and overwrites OS X-bundled executables, causing a risk of it being overwritten by a new (yet possibly outdated) version of as bundled with a future version of OS X.
Is there then a better workaround?
As noted on Why does cross gcc invoke native 'as'? it seems to be possible to specify which "as"-executable and flags to use (using "-specs=..."). A cleaner workaround to the problem seems to be to pass the correct "-specs" flags to invoke the clang assembler. This does not require admin privileges and does not risk being broken by an OS X update. The exact details of how to perform this remains to be found out (anyone?).
If this workaround becomes trouble-free and transparent enough, it may be warranted to use those settings as a default (or at least variant) for the macport gcc (so that it supports "-march=native" and the like). There is such as configure.args setting ("--with-as=${prefix}/bin/as", as seen in https://trac.macports.org/browser/trunk/dports/lang/gcc48/Portfile ), which could be replaced.