High Availability of Namenode has been introduced with Hadoop 2.x release.
It can be achieved in two modes - With NFS and With QJM
But high availability with Quorum Journal Manager (QJM) is preferred option.
In a typical HA cluster, two separate machines are configured as NameNodes. At any point in time, exactly one of the NameNodes is in an Active state, and the other is in a Standby state. The Active NameNode is responsible for all client operations in the cluster, while the Standby is simply acting as a slave, maintaining enough state to provide a fast failover if necessary.
Have a look at below SE questions, which explains complete failover process.
Secondary NameNode usage and High availability in Hadoop 2.x
How does Hadoop Namenode failover process works?