I'm not sure when exactly it appeared (possibly Mar-Apr 2019), but it is now available on Mathworks' GitHub. Here's the grammar-defining xml file (as of 09-Apr-2019; compressed to avoid the SO post character limit):
Copyright 2018 The MathWorks, Inc., under the BSD2 license.
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symbols</string><key>match</key><string>((\%([\+\-0]?\d{0,3}(\.\d{1,3})?)(c|d|e|E|f|g|G|s|((b|t)?(o|u|x|X))))|\%\%|\\(b|f|n|r|t|\\))</string><key>name</key><string>constant.character.escape.matlab</string></dict></array></dict><dict><key>begin</key><string>((?<=(\[|\(|\{|=|\s|;|:|,|~|<|>|&|\||-|\+|\*|/|\\|\.|\^))|^)"</string><key>beginCaptures</key><dict><key>0</key><dict><key>name</key><string>punctuation.definition.string.begin.matlab</string></dict></dict><key>comment</key><string>String literal (double-quoted)</string><key>end</key><string>"(?=(\[|\(|\{|\]|\)|\}|=|~|<|>|&|\||-|\+|\*|/|\\|\.|\^|\||\s|;|:|,))</string><key>endCaptures</key><dict><key>0</key><dict><key>name</key><string>punctuation.definition.string.end.matlab</string></dict></dict><key>name</key><string>string.quoted.double.matlab</string><key>patterns</key><array><dict><key>match</key><string>""</string><key>name</key><string>constant.character.escape.matlab</string></dict><dict><key>match</key><string>"(?=.)</string><key>name</key><string>invalid.illegal.unescaped-quote.matlab</string></dict></array></dict></array></dict><key>transpose</key><dict><key>match</key><string>((\w+)|(?<=\])|(?<=\)))\.?'</string><key>name</key><string>keyword.operator.transpose.matlab</string></dict><key>constants</key><dict><key>comment</key><string>MATLAB Constants</string><key>match</key><string>(?<!\.)\b(eps|false|Inf|inf|intmax|intmin|namelengthmax|NaN|nan|on|off|realmax|realmin|true|pi)\b</string><key>name</key><string>constant.language.matlab</string></dict><key>variables</key><dict><key>comment</key><string>MATLAB variables</string><key>match</key><string>(?<!\.)\b(nargin|nargout|varargin|varargout)\b</string><key>name</key><string>variable.other.function.matlab</string></dict><key>end_in_parens</key><dict><key>comment</key><string>end as operator symbol</string><key>match</key><string>\bend\b</string><key>name</key><string>keyword.operator.symbols.matlab</string></dict><key>numbers</key><dict><key>comment</key><string>Valid numbers: 1, .1, 1.1, .1e1, 1.1e1, 1e1, 1i, 1j, 1e2j</string><key>match</key><string>(?<=[\s\-\+\*\/\\=:\[\(\{,]|^)\d*\.?\d+([eE][+-]?\d)?([0-9&&[^\.]])*(i|j)?\b</string><key>name</key><string>constant.numeric.matlab</string></dict><key>operators</key><dict><key>comment</key><string>Operator symbols</string><key>match</key><string>(?<=\s)(==|~=|>|>=|<|<=|&|&&|:|\||\|\||\+|-|\*|\.\*|/|\./|\\|\.\\|\^|\.\^)(?=\s)</string><key>name</key><string>keyword.operator.symbols.matlab</string></dict></dict><key>scopeName</key><string>source.matlab</string><key>uuid</key><string>48F8858B-72FF-11D9-BFEE-000D93589AF6</string></dict></plist>