I am not clear whether you want to install or just view the contents of VSIX. If you want to install the extension, you just need to double click it and it will install (Do not try to open it with VS Version selector). If you want to see what is inside VSIX, it is basically an archive. So either try to use program like 7-zip to open it else, rename .vsix to .zip and then unzip it.
Further, there is also a chance that you have wrongly associated vsix files to be opened with Visual Studio. In such a case it will open in Visual Studio any case.
Finally, if you have wrongly associated the vsix to open with Visual Studio, try installing the extension using VSIXInstaller.exe found in C:\Program Files (x86)\Microsoft Visual Studio 12.0\Common7\IDE\VSIXInstaller.exe