PHP is a compiled language since PHP 4.0
The idea of what is a compiler seems to be a subject that causes great confusion. Some people assume that a compiler is a program that converts source code in one language into an executable program. The definition of what is a compiler is actually broader than that.
A compiler is a program that transforms source code into another representation of the code. The target representation is often machine code, but it may as well be source code in another language or even in the same language.
PHP became a compiled language in the year 2000, when PHP 4 was released for the first time. Until version 3, PHP source code was parsed and executed right away by the PHP interpreter.
PHP 4 introduced the the Zend engine. This engine splits the processing of PHP code into several phases. The first phase parses PHP source code and generates a binary representation of the PHP code known as Zend opcodes. Opcodes are sets of instructions similar to Java bytecodes. These opcodes are stored in memory. The second phase of Zend engine processing consists in executing the generated opcodes.
Form more information go to http://www.phpclasses.org/blog/post/117-PHP-compiler-performance.html