I've found a strange behaviour in Nmap (I am using version 5.51 if that matters but I have the same issue with version 5.00), on some networks this plugin does not retrieve MAC address and, consequently, Vendor. The strange thing is that it retrieves almost everything like operating system and so on but it does not print the MAC address. How is that possible? This is the command I use usually:
nmap -A -O 192.168.1.0/24 -oX mynetwork.xml