Distributing apps outside store is possible after complying to the prerequisites listed in this MSDN article. It also covers the process of application installation using PowerShell. Though it appears quite complicated, note that MSIs work fine for Windows 8 metro apps so you can probably enclose the installation process into one small instalator.
From the article
- Requires Windows 8 Enterprise Edition, and must be joined to a domain, and the domain must have the Allow all trusted applications to install Group Policy setting.
- for Windows 8 Professional, and Windows RT, or a non-domain joined machine, you must buy a sideloading product activation key from Microsoft
- the application must be signed by a key that is trusted by the computer
Once you've purchased your sideloading product key from Microsoft, add the sideloading product key:
>Slmgr /ipk <sideloading product key>
To enable side-loading, enable the following guid:
>slmgr /ato ec67814b-30e6-4a50-bf7b-d55daf729d1e
To add an application, from a powershell prompt:
>add-appxpackage C:\app1.appx –DependencyPath C:\winjs.appx
Windows 8.1 Update
According to the latest announcements by Microsoft the next update to Windows 8.1 will allow all the devices running the Pro version to sideload applications without sideloading activation key. So far this has been the case only for the Enterprise version. Bare in mind that the machine will still need to be a part of the AD domain. Additionally, if you still run a previous version but you're part of any of the below programs:
- Enterprise Agreement
- Enterprise Subscription Agreement
- Enrollment for Education Solutions (under a Campus and School Agreement)
- School Enrollment
- Select and Select Plus
You'll be granted the enterprise sideloading rights starting on the 1st of May 2014. Otherwise you'll still be able to sideload but will need to buy a sideloading activation key for 100$ (that's a one-time charge for an unlimited number of devices).