I believe the WAVE module does not support recording, just processing existing files. You might want to look at PyAudio for actually recording.
WAV is about the world's simplest file format. In paInt16 you just get a signed integer representing a level, and closer to 0 is quieter. I can't remember if WAV files are high byte first or low byte, but something like this ought to work (sorry, I'm not really a python programmer:
from array import array
# you'll probably want to experiment on threshold
# depends how noisy the signal
threshold = 10
max_value = 0
as_ints = array('h', data)
max_value = max(as_ints)
if max_value > threshold:
# not silence
PyAudio code for recording kept for reference:
import pyaudio
import sys
chunk = 1024
FORMAT = pyaudio.paInt16
CHANNELS = 1
RATE = 44100
RECORD_SECONDS = 5
p = pyaudio.PyAudio()
stream = p.open(format=FORMAT,
channels=CHANNELS,
rate=RATE,
input=True,
output=True,
frames_per_buffer=chunk)
print "* recording"
for i in range(0, 44100 / chunk * RECORD_SECONDS):
data = stream.read(chunk)
# check for silence here by comparing the level with 0 (or some threshold) for
# the contents of data.
# then write data or not to a file
print "* done"
stream.stop_stream()
stream.close()
p.terminate()