No that isn't possible now. What you could do is move those collections into another unreplicated database. But this will cause headaches once these collections see higher traffic too, so you would need to move them into your "replication"-db.
But in general Replication isn't the way to go if you need to scale, it's more considered for DR/failover. Replicaset Secondaries can only (optionally) answer read queries but no write queries, this is something you should keep in mind. So if you have high write load this may not cure your problem.
Once you allow your application to read from secondaries you need to live with eventual consistency, meaning that your application isn't guaranteed to see always the latest data. This is caused due to the asynchronous replication to the secondaries.
Indeed you can cure this problem if you configure your writeconcern, so that the write needs to succeeded on all replicas, before it's considered written and your driver returns. But this may slow down your write operations significant.
So for scaling query execution capabilities I would go with Sharding. This is possible on a per collection level, all unsharded collections will remain on a "default-shard".