The 0x16, 0x20 and 0x21 byte values you see in advertisements are advertising "AD" types that indicate the following bytes include the GATT Service UUID of the specified length for the type, followed by service data. See here for the full list of AD type values.
In beacon advertisements it is most common to use the 16-bit UUID since that UUID length it takes up the least amount of space in the advertisement packet, leaving the most bytes remaining for data. The 16-bit service UUIDs you mention (e.g. 0x6e2A) are in theory registered with Bluetooth SIG, and there is indeed a list of them. There are a few different types:
- Public GATT Services
- Private GATT Services of Bluetooth SIG members
- GATT Services of standards development organizations
The first list is for public specifications that anyone can implement. The second two lists are for private specifications. The numbers are reserved, but the way thy are used are proprietary to the organization that owns the number assignment.
If you look through these lists, you'll note you will not find the 6E2A number you mention. How can that be?
There is nothing stopping people from building bluetooth devices that use 16-bit service UUIDs without registering them. Registering costs money and takes time. So lots of projects skip that step, especially in development, even if it is considered bad behavior to be frowned upon by Bluetooth SIG.
For "black market" GATT services like this, there is simply no way to find out a full list of those that exist. You can only look for them on-by-one and reverse-engineer them. Or you can beg the manufacturer for documentation.
Further, regardless of whether the Service UUIDs are registered with Bluetooth SIG, the service data bytes that follow the UUID are not standardized. The manufacturer of the device advertising the service data is allowed to encode whatever data in these bytes that he or she wishes for the specific use case. So unfortunately there is no central registry of what they mean. Meaning has to come from either documentation from the manufacturer or reverse engineering.