There's a C# sample here:
http://aws.amazon.com/code/Product-Advertising-API/3941
FWIW, the AWS thread I mentioned includes these steps for a workaround:
These are the steps as of January 31, 2012 to fix this issue in Visual
Studio for .Net clients:
1) Click the "Show all files" button in the Solution Explorer for the
project containing the amazon service reference.
2) Expand the
reference and open the AWSECommerceService.wsdl file in the editor
3)
On line 584 change the "maxOccurs' to "1".
<xs:element minOccurs="0" maxOccurs="1" name="ImageSets">
4) Save the AWSECommerceService.wsdl file
5) Right click
Reference.svcmap and click "Run custom tool"
6) Expand
Reference.svcmap and open either Reference.cs or Reference.vb