no, you cannot have, and you don't need a separate %install section.
Let's suppose a typical example: you compile a program and want to create two packages; library.rpm and library-devel.rpm (with the headers). Then you'll have a spec file something like this:
Name: library
# probably some other fields...
%description
describre library
%package devel
Summary: headers for library
%description devel
describe library-devel package
%prep
# some common prep code for both packages; eg
%setup -q
%build
make (or whatever to build your program)
%install
# install files for both rpm packages; library AND headers
mkdir -p ${RPM_BUILD_ROOT}/%_libdir/
mkdir -p ${RPM_BUILD_ROOT}/usr/include/
cp library.so* ${RPM_BUILD_ROOT}/%_libdir/
cp include/*.h* ${RPM_BUILD_ROOT}/usr/include/
%files
%defattr(-,root,root)
%_libdir/*.so.*
%files devel
%defattr(-,root,root)
%_libdir/*.so # yes; if you use version numbers; the versioned .so go in the normal package; the one without version number in the devel package
/usr/include/*
further reading: RPM packaging guide
%install
is at RPM build time. The scriptlets are executed at install time, e.g.%post
. Those allow subpackages. – Derwon