Slack does not track user login or logoff in a traditional sense. Instead, users are always always "logged in" and available to receive messages once they have joined a team / channel.
There also is the concept of "presence", which is related, but not the same thing. User presence can change multiple times during a few minutes, e.g. if the user is on a mobile. I am guessing you would not want to send the user your message that often.
Still you can poll the presence information of a user with the API users.getPresence
, which could be used to implement a script that polls this information on a regular basis and send your message. You also want to filter out presence changes below a certain duration threshold.
Keep in mind though that the rate limit for API methods is 1 per second. So depending on how many users you have in your workspace there will be a significant delay between the user becoming "present" and your script being able to send the message.