If you have a good reason to set aside culture-dependent formatting and get explicit control over whether or not there's a space between the value and the "%", and whether the "%" is leading or trailing, you can use NumberFormatInfo's PercentPositivePattern and PercentNegativePattern properties.
For example, to get a decimal value with a trailing "%" and no space between the value and the "%":
myValue.ToString("P2", new NumberFormatInfo { PercentPositivePattern = 1, PercentNegativePattern = 1 });
More complete example:
using System.Globalization;
...
decimal myValue = -0.123m;
NumberFormatInfo percentageFormat = new NumberFormatInfo { PercentPositivePattern = 1, PercentNegativePattern = 1 };
string formattedValue = myValue.ToString("P2", percentageFormat); // "-12.30%" (in en-us)
P
formatting? – Allare