I try this:
PlayMusic = new MediaElement();
PlayMusic.AudioCategory = Windows.UI.Xaml.Media.AudioCategory.Media;
PlayMusic.Source = new Uri(@"C:\Users\UserName\Desktop\C:\Users\user\Desktop\Kill The Alarm - Begin Again.mp3");
PlayMusic.Play();
No more error messages appear on the display (try catch runs clean through).
Sorry for the short description... I can read and understand English very well but it is difficult for me to talk and write.
C:\Users\UserName\Desktop\C:\Users\paulk\Desktop\Kill The Alarm - Begin Again.mp3
is not a valid path, you're repeating the substring to your Desktop folder. – Enrich