There is no way you can do that by using FillSchema. For details check link below
http://msdn.microsoft.com/en-us/library/229sz0y5.aspx
INFORMATION_SCHEMA is the place where you should look. INFORMATION_SCHEMA contains many system views which can show you details of database structure. for example
INFORMATION_SCHEMA.TABLES : shows you list of tables in the database
INFORMATION_SCHEMA.COLUMNS : shows you list of Columns and their attributes in all tables of the database. Please look at following location for more detail.
http://msdn.microsoft.com/en-us/library/ms186778.aspx
To get default value using query you can use following query:
SELECT *
FROM INFORMATION_SCHEMA.Columns
WHERE TABLE_NAME = 'YourTableName'